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Design and Synthesis of Dioxetane-Based Chemiluminescent Substrates with High Efficiency in Aqueous System(By a grant Research Institute for Integrated Science, Kanagawa University)
http://hdl.handle.net/10487/1438
http://hdl.handle.net/10487/14386be9d5a4-dcf8-4761-8c8f-9fe435c5ced2
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2009-02-23 | |||||
タイトル | ||||||
タイトル | Design and Synthesis of Dioxetane-Based Chemiluminescent Substrates with High Efficiency in Aqueous System(By a grant Research Institute for Integrated Science, Kanagawa University) | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | dioxetane | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | chemiluminescence | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | hydrogen bonding | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
Matsumoto, Masakatsu
× Matsumoto, Masakatsu× 松本, 正勝× Watanabe, Nobuko× 渡辺, 信子× Ohashi, Mamoru× 大橋, 守× Fujimori, Ken× 藤森, 憲 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The chemiluminescent efficiency of hydroxyphenyl-substituted dioxetanes is well known to decrease significantly in an aqueous medium, though more than bioluminescence in an aprotic medium. We investigated here the effect of hydrogen bonding on singlet-chemiexcitation and fluorescence efficiency of the emitter produced for charge-transfer-induced chemiluminescence by the use of dioxetanes bearing a 3-hydroxyphenyl moiety substituted with a proton-donating group at the 4-position as a model substrate. Based on this investigation, four bicyclic dioxetanes bearing a 4-(benzoazol-2-yl)-3-hydroxyphenyl moiety were designed and synthesized. The thus-realized dioxetanes exhibited chemiluminescence with markedly high efficiency in aqueous medium as well as in aprotic medium. | |||||
書誌情報 |
Science Journal of Kanagawa University 巻 17, p. 83-84, 発行日 2006-05-25 |
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収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1880-0483 | |||||
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収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12068302 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 神奈川大学 |