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Design and Synthesis of Dioxetane-Based Chemiluminescent Substrates with High Efficiency in Aqueous System(By a grant Research Institute for Integrated Science, Kanagawa University)
http://hdl.handle.net/10487/1438
http://hdl.handle.net/10487/14386be9d5a4-dcf8-4761-8c8f-9fe435c5ced2
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
kana-2-2-0012.pdf (628.5 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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| 公開日 | 2009-02-23 | |||||
| タイトル | ||||||
| タイトル | Design and Synthesis of Dioxetane-Based Chemiluminescent Substrates with High Efficiency in Aqueous System(By a grant Research Institute for Integrated Science, Kanagawa University) | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | dioxetane | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | chemiluminescence | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | hydrogen bonding | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
Matsumoto, Masakatsu
× Matsumoto, Masakatsu× 松本, 正勝× Watanabe, Nobuko× 渡辺, 信子× Ohashi, Mamoru× 大橋, 守× Fujimori, Ken× 藤森, 憲 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The chemiluminescent efficiency of hydroxyphenyl-substituted dioxetanes is well known to decrease significantly in an aqueous medium, though more than bioluminescence in an aprotic medium. We investigated here the effect of hydrogen bonding on singlet-chemiexcitation and fluorescence efficiency of the emitter produced for charge-transfer-induced chemiluminescence by the use of dioxetanes bearing a 3-hydroxyphenyl moiety substituted with a proton-donating group at the 4-position as a model substrate. Based on this investigation, four bicyclic dioxetanes bearing a 4-(benzoazol-2-yl)-3-hydroxyphenyl moiety were designed and synthesized. The thus-realized dioxetanes exhibited chemiluminescence with markedly high efficiency in aqueous medium as well as in aprotic medium. | |||||
| 書誌情報 |
Science Journal of Kanagawa University 巻 17, p. 83-84, 発行日 2006-05-25 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学 | |||||
