{"created":"2023-05-15T11:46:23.942699+00:00","id":6928,"links":{},"metadata":{"_buckets":{"deposit":"eb8fb4ec-8dac-4d7b-98e0-164b509030be"},"_deposit":{"created_by":1,"id":"6928","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"6928"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00006928","sets":["376:377:378:556"]},"author_link":["20730","20731","20732","20733","20729","20734","20735","20736"],"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-05-25","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"84","bibliographicPageStart":"83","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The chemiluminescent efficiency of hydroxyphenyl-substituted dioxetanes is well known to decrease significantly in an aqueous medium, though more than bioluminescence in an aprotic medium. We investigated here the effect of hydrogen bonding on singlet-chemiexcitation and fluorescence efficiency of the emitter produced for charge-transfer-induced chemiluminescence by the use of dioxetanes bearing a 3-hydroxyphenyl moiety substituted with a proton-donating group at the 4-position as a model substrate. Based on this investigation, four bicyclic dioxetanes bearing a 4-(benzoazol-2-yl)-3-hydroxyphenyl moiety were designed and synthesized. The thus-realized dioxetanes exhibited chemiluminescence with markedly high efficiency in aqueous medium as well as in aprotic medium.","subitem_description_type":"Abstract"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matsumoto, Masakatsu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"松本, 正勝"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Watanabe, Nobuko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"渡辺, 信子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohashi, Mamoru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大橋, 守"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujimori, Ken"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"藤森, 憲"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"kana-2-2-0012.pdf","filesize":[{"value":"628.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kana-2-2-0012.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/6928/files/kana-2-2-0012.pdf"},"version_id":"e843155b-8119-4438-93a6-f84472b2e3df"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"dioxetane","subitem_subject_scheme":"Other"},{"subitem_subject":"chemiluminescence","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrogen bonding","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Design and Synthesis of Dioxetane-Based Chemiluminescent Substrates with High Efficiency in Aqueous System(By a grant Research Institute for Integrated Science, Kanagawa University)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Design and Synthesis of Dioxetane-Based Chemiluminescent Substrates with High Efficiency in Aqueous System(By a grant Research Institute for Integrated Science, Kanagawa University)"}]},"item_type_id":"3","owner":"1","path":["556"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-23"},"publish_date":"2009-02-23","publish_status":"0","recid":"6928","relation_version_is_last":true,"title":["Design and Synthesis of Dioxetane-Based Chemiluminescent Substrates with High Efficiency in Aqueous System(By a grant Research Institute for Integrated Science, Kanagawa University)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T15:45:20.055012+00:00"}