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環境調和型錯体の特長を生かした新規酸化触媒の創成とエネルギー・環境問題への展開(2004-2005年度神奈川大学共同研究奨励助成論文)
http://hdl.handle.net/10487/1446
http://hdl.handle.net/10487/1446a4aae625-f7fd-47de-a76d-0c56f0c86c3d
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SJKU Vol 17 31-37.pdf (913.9 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2009-02-23 | |||||
| タイトル | ||||||
| タイトル | 環境調和型錯体の特長を生かした新規酸化触媒の創成とエネルギー・環境問題への展開(2004-2005年度神奈川大学共同研究奨励助成論文) | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | polyoxotungstate | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | microporous copper (II) carboxylate | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | alkene epoxidation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | alcohol oxidation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | grafting method | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
加藤, 知香
× 加藤, 知香× Kato, Nozaki Chika× 野宮, 健司× Nomiya, Kenji× 森, 和亮× Mori, Wasuke× 鈴木, 季直× Suzuki, Suechika |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The oxidation of alkenes and alcohols with hydrogen peroxide (H_2O_2) and molecular oxygen, is quite an interesting objective for both academic and industrial fields. In this paper, we focused on polyoxometalates and microporous transition metal carboxylates as oxidation catalysts. For H_2O_2-based epoxidation reactions catalyzed by dimeric mono, di, and trititanium (IV)-substituted Keggin polyoxotungstates, trititanium (IV)-substituted Keggin polyoxotungstate was the most active because it exhibited the fastest formation rate of active hydroperoxotitanium (IV) intermediate. Furthermore, we investigated a novel method for the grafting reaction of transition metal-substituted polyoxometalates onto a silica surface. Keggin-type vanadium(V)-substituted polyoxomolybdate (PMoV) was electrostatically anchored to a modified silica surface having cationic ammonium moiety. The PMoV-grafted silica material exhibited activities higher than those of homogeneous PMoV reactions for the oxidation of various alcohols with 1 atm dioxygen in the presence of isobutyraldehyde (IBA). Microporous copper(II) carboxylates showed unique activities for the oxidation of alcohols with H_2O_2 in a heterogeneous system, in which a green-colored species, H_2[Cu_2^<II,II>(OOCC_6H_10COO)_2(O_2)]・H_2O was one of the active oxidizing intermediates. | |||||
| 書誌情報 |
Science Journal of Kanagawa University 巻 17, p. 31-37, 発行日 2006-05-25 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| その他の言語のタイトル | ||||||
| その他のタイトル | Polyoxometalates and Microporous Transition Metal Carboxylates: Synthesis, Characterization, and Oxidation Catalysis | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学 | |||||
