{"created":"2023-05-15T11:46:23.628085+00:00","id":6921,"links":{},"metadata":{"_buckets":{"deposit":"1590b26e-f589-4622-a8a2-ad6aa0d7c1e5"},"_deposit":{"created_by":1,"id":"6921","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"6921"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00006921","sets":["376:377:378:556"]},"author_link":["20678","20676","20674","20673","20677","20672","20675","20671"],"item_3_alternative_title_20":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Polyoxometalates and Microporous Transition Metal Carboxylates: Synthesis, Characterization, and Oxidation Catalysis"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-05-25","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"37","bibliographicPageStart":"31","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The oxidation of alkenes and alcohols with hydrogen peroxide (H_2O_2) and molecular oxygen, is quite an interesting objective for both academic and industrial fields. In this paper, we focused on polyoxometalates and microporous transition metal carboxylates as oxidation catalysts. For H_2O_2-based epoxidation reactions catalyzed by dimeric mono, di, and trititanium (IV)-substituted Keggin polyoxotungstates, trititanium (IV)-substituted Keggin polyoxotungstate was the most active because it exhibited the fastest formation rate of active hydroperoxotitanium (IV) intermediate. Furthermore, we investigated a novel method for the grafting reaction of transition metal-substituted polyoxometalates onto a silica surface. Keggin-type vanadium(V)-substituted polyoxomolybdate (PMoV) was electrostatically anchored to a modified silica surface having cationic ammonium moiety. The PMoV-grafted silica material exhibited activities higher than those of homogeneous PMoV reactions for the oxidation of various alcohols with 1 atm dioxygen in the presence of isobutyraldehyde (IBA). Microporous copper(II) carboxylates showed unique activities for the oxidation of alcohols with H_2O_2 in a heterogeneous system, in which a green-colored species, H_2[Cu_2^<II,II>(OOCC_6H_10COO)_2(O_2)]・H_2O was one of the active oxidizing intermediates.","subitem_description_type":"Abstract"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"加藤, 知香"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kato, Nozaki Chika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"野宮, 健司"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nomiya, Kenji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森, 和亮"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mori, Wasuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鈴木, 季直"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Suzuki, Suechika"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"SJKU Vol 17 31-37.pdf","filesize":[{"value":"913.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SJKU Vol 17 31-37.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/6921/files/SJKU Vol 17 31-37.pdf"},"version_id":"8ea7ace7-82b3-4a56-bb53-fee16f5e20dc"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"polyoxotungstate","subitem_subject_scheme":"Other"},{"subitem_subject":"microporous copper (II) carboxylate","subitem_subject_scheme":"Other"},{"subitem_subject":"alkene epoxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"alcohol oxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"grafting method","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"環境調和型錯体の特長を生かした新規酸化触媒の創成とエネルギー・環境問題への展開(2004-2005年度神奈川大学共同研究奨励助成論文)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"環境調和型錯体の特長を生かした新規酸化触媒の創成とエネルギー・環境問題への展開(2004-2005年度神奈川大学共同研究奨励助成論文)"}]},"item_type_id":"3","owner":"1","path":["556"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-23"},"publish_date":"2009-02-23","publish_status":"0","recid":"6921","relation_version_is_last":true,"title":["環境調和型錯体の特長を生かした新規酸化触媒の創成とエネルギー・環境問題への展開(2004-2005年度神奈川大学共同研究奨励助成論文)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T15:45:27.425952+00:00"}