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Stereoselective construction of 3a-methylhydrindanes starting from 2,7-enynol derivatives based on Ti(II)-mediated cyclization and Ru-catalyzed ring-closing metathesis
http://hdl.handle.net/10487/8225
http://hdl.handle.net/10487/82259bf4c56b-308b-4ead-87a2-aed3994aa689
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
20okamoto.pdf (378.6 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2011-02-04 | |||||
| タイトル | ||||||
| タイトル | Stereoselective construction of 3a-methylhydrindanes starting from 2,7-enynol derivatives based on Ti(II)-mediated cyclization and Ru-catalyzed ring-closing metathesis | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Okubo, Mutsumi
× Okubo, Mutsumi× Uchikawa, Wataru× Matsushita, Hitomi× Nakano, Aiko× Shirato, Takayuki× 岡本, 専太郎× Okamoto, Sentaro |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The Ti(II)-mediated cyclization of 3-methyloct-2-en-7-yn-1-ol derivatives 2 proceeded stereoselectively to afford 1-methyl-2-(1-alkylbut-3-enylidene)-1-vinylcyclopentanes 3 after treatment of the resulting alkenyltitaniums with allylbromide in the presence of CuCN, which was readily converted to 3a-methyl-2,3,3a,6-tetrahydro-1H-indenes 1 by the Ru-catalyzed ring-closing metathesis. | |||||
| 書誌情報 |
Tetrahedron Letters 巻 47, 号 29, p. 5181-5185, 発行日 2006-07-17 |
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| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.tetlet.2006.05.030 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | Elsevier | |||||
| 資源タイプ | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
