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反応のタイプと発見のエピソードで学ぶ有機金属化学（12）
https://doi.org/10.24792/0002001010
https://doi.org/10.24792/0002001010c6814947-ac71-4cb6-8d23-e47ff7a9e029
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
11 反応のタイプと発見のエピソードで学ぶ有機金属化学（12）.pdf (1.2 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2024-09-20 | |||||
| タイトル | ||||||
| タイトル | 反応のタイプと発見のエピソードで学ぶ有機金属化学（12） | |||||
| 言語 | ja | |||||
| タイトル | ||||||
| タイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (12) | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | π-π bond metathesis | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Schrock Mo-carbene catalyst | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Grubbs Ru-carbene catalyst | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| ID登録 | ||||||
| ID登録 | 10.24792/0002001010 | |||||
| ID登録タイプ | JaLC | |||||
| 著者 |
加部, 義夫
× 加部, 義夫 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds have been known and studied since the 19th century and have been widely used to effect synthetic transformation in modern organic chemistry. Many educational benefits may result from the use of reaction types and discovery episodes for undergraduate and graduate classes in organic and organometallic chemistry. Organometallic reactions were categorized into several types of metathesis reaction, depending on the combination of σ and π-bonds, such as σ-σ bond , σ-π bond, and π-π bond metathesis. Most early work in π-π bond metathesis reactions was conducted using ill-defined multicomponent catalyst systems. In 1971, Chauvin proposed the now widely accepted metal carbene mechanism, which was described in a previous article in this series. Subsequently, in the early 1990s, Schrock and Grubbs reported the well defined single component Mo- and Ru-carbene complex catalysts, respectively. In this article, discoveries and the development of these Mo- and Ru-carbene catalysts are outlined. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 教育論文 | |||||
| 言語 | ja | |||||
| 書誌情報 |
ja : Science Journal of Kanagawa University en : Science Journal of Kanagawa University 巻 35, p. 63-75, 発行日 2023-07-30 |
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| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 出版タイプ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学総合理学研究所 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | Research Institute for Integrated Science, Kanagawa University | |||||
| 言語 | en | |||||
