{"created":"2024-09-20T00:17:43.782684+00:00","id":2001010,"links":{},"metadata":{"_buckets":{"deposit":"5d3feced-ec22-4f0e-8a35-4c748f2526bc"},"_deposit":{"created_by":10,"id":"2001010","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"2001010"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:02001010","sets":["376:377:378:1726789902848"]},"author_link":["33604"],"control_number":"2001010","item_3_biblio_info_7":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-07-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"75","bibliographicPageStart":"63","bibliographicVolumeNumber":"35","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University","bibliographic_titleLang":"ja"},{"bibliographic_title":"Science Journal of Kanagawa University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds have been known and studied since the 19th century and have been widely used to effect synthetic transformation in modern organic chemistry. Many educational benefits may result from the use of reaction types and discovery episodes for undergraduate and graduate classes in organic and organometallic chemistry. Organometallic reactions were categorized into several types of metathesis reaction, depending on the combination of σ and π-bonds, such as σ-σ bond , σ-π bond, and π-π bond metathesis. Most early work in π-π bond metathesis reactions was conducted using ill-defined multicomponent catalyst systems. In 1971, Chauvin proposed the now widely accepted metal carbene mechanism, which was described in a previous article in this series. Subsequently, in the early 1990s, Schrock and Grubbs reported the well defined single component Mo- and Ru-carbene complex catalysts, respectively. In this article, discoveries and the development of these Mo- and Ru-carbene catalysts are outlined.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"教育論文","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_identifier_registration":{"attribute_name":"identifier_registration","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24792/0002001010","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学総合理学研究所","subitem_publisher_language":"ja"},{"subitem_publisher":"Research Institute for Integrated Science, Kanagawa University","subitem_publisher_language":"en"}]},"item_3_source_id_10":{"attribute_name":"item_3_source_id_10","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"item_3_source_id_8","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"PISSN"}]},"item_3_version_type_16":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"加部, 義夫","creatorNameLang":"ja"},{"creatorName":"カベ, ヨシオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"33604","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"33604","nameIdentifierScheme":"ローカル著者ID"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"11 反応のタイプと発見のエピソードで学ぶ有機金属化学（12）.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kanagawa-u.repo.nii.ac.jp/record/2001010/files/11 反応のタイプと発見のエピソードで学ぶ有機金属化学（12）.pdf"},"version_id":"d02e9b52-6be8-4d1b-89af-e20dee8d3ee8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"π-π bond metathesis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Schrock Mo-carbene catalyst","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Grubbs Ru-carbene catalyst","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"反応のタイプと発見のエピソードで学ぶ有機金属化学（12）","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"反応のタイプと発見のエピソードで学ぶ有機金属化学（12）","subitem_title_language":"ja"},{"subitem_title":"Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (12)","subitem_title_language":"en"}]},"item_type_id":"3","owner":"10","path":["1726789902848"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-09-20"},"publish_date":"2024-09-20","publish_status":"0","recid":"2001010","relation_version_is_last":true,"title":["反応のタイプと発見のエピソードで学ぶ有機金属化学（12）"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2024-10-09T06:54:09.257273+00:00"}