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反応のタイプと発見のエピソードで学ぶ有機金属化学(9)
http://hdl.handle.net/10487/00017138
http://hdl.handle.net/10487/000171381b102704-a08b-4c9c-9941-c47d71d6f265
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
15 反応のタイプと発見のエピソードで学ぶ有機金属化学(9) (1.7 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2021-08-18 | |||||
| タイトル | ||||||
| タイトル | 反応のタイプと発見のエピソードで学ぶ有機金属化学(9) | |||||
| 言語 | ja | |||||
| タイトル | ||||||
| タイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (9) | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Heck reaction | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Kharasch | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | cross coupling | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | nickel | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | palladium catalyst | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Heck reaction | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Kharasch | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | cross coupling | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | nickel | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | palladium catalyst | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
加部, 義夫
× 加部, 義夫 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Organic compounds containing carbon-metal bonds are called organometallic com- pounds. Such compounds have been known and studied since the 19th century and have been widely used to modify synthetic transformation in modern organic chemistry. It is considered that many educational benefits could result in the use of reaction types and discovery episode for undergraduates and graduate classes in organic and organometallic chemistry. In 1968, Heck began to investigate reactions of phenyl mercury acetate with Li2[PdCl4] solution under an ethylene atomosphere to produce styrene. Due to the high toxicity of mercury, he changed to the direct coupling of aryl iodide with ethylene in the presence of a palladium catalyst, the so-called Heck reaction. In the 1940's, Kharasch investigated the Grignard reaction in the presence of catalytic amounts of salts of transition metals to produce homo and cross-coupling products with organic halides, considered to be produced by a radical mechanism. In 1970-72, several revolutionary findings by Yamamoto, Kochi, Corriu, Kumada, and Tamao odified this Griganrd reaction with Ag, Cu, Fe, and Ni catalysts, which is now available as a modern Pd catalyzed cross-coupling reaction that is synthetically powerful, devised by Negishi, Sonogashi-ra, Migita, Kosugi, Suzuki, Miyaura, and Hiyama. The mechanism of reaction was disclosed as oxidative addition and reductive elimination of low valent Pd(0) in the catalytic cycle. |
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| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 教育論文 | |||||
| 書誌情報 |
en : Science Journal of Kanagawa University 巻 32, p. 97-105, 発行日 2021-06-30 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| その他の言語のタイトル | ||||||
| その他のタイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (9) | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学総合理学研究所 | |||||
| 出版者 | ||||||
| 出版者 | Research Institute for Integrated Science, Kanagawa University | |||||
| 資源タイプ | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Departmental Bulletin Paper | |||||
