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ナノ細孔をもつカルボン酸金属錯体をベースとした新しい固体触媒の構築と地球環境改善への展開(2005年度神奈川大学総合理学研究所助成共同研究)
http://hdl.handle.net/10487/1449
http://hdl.handle.net/10487/14499452bc87-d041-4db5-bb09-c18fb116e8a3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
kana-2-2-0014.pdf (567.3 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2009-02-23 | |||||
| タイトル | ||||||
| タイトル | ナノ細孔をもつカルボン酸金属錯体をベースとした新しい固体触媒の構築と地球環境改善への展開(2005年度神奈川大学総合理学研究所助成共同研究) | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | microporous iron(III) carboxylate / metalloporphyrin / photo-oxidation / visiblelight irradiation | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
森, 和亮
× 森, 和亮× Mori, Wasuke× 加藤, 知香× Kato, Nozaki Chika |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The photo-oxidation catalysis of hydrocarbons with 1 atm dioxygen in a heterogeneous system is quite an interesting objective for both academic and industrial fields. The remarkable progress of the past decade in photocatalysis has been limited to ultraviolet light instead of the more useful visible-light region. The development of visible-light photocatalysts, therefore, has become one of the most important topics in photocatalysis research today. Here, we focused on the synthesis of novel microporous iron(III) carboxylate complexes having metalloporphyrins, Fe[MTCPP](M=Cu, Fe, Pd, Mn, Co; H_2TCPP=4,4',4'',4'''-(21H, 23H-porphine-5, 10, 15, 20-tetrayl) tetrakis benzoic acid). The complexes were characterized by elemental analysis, TG/DTA, magnetic susceptibility, FT-IR, diffuse reflectance (DR) UV-vis, EPR, EXAFS, BET surface area, pore size distribution, and nitrogen occlusion measurements. In the DRUV-vis spectra, the iron complexes showed some adsorption bands in the visible-light region. Therefore, we demonstrated the catalytic activities of Fe[MTCPP] complexes for the photo-oxidation of hydrocarbons with 1 atm dioxygen under visible-light irradiation. Fe[PdTCPP] showed 37 turnover numbers after 3h for the photo-oxidation of cyclohexene, which was higher than those of the other iron(III) carboxylate complexes. | |||||
| 書誌情報 |
Science Journal of Kanagawa University 巻 17, p. 89-90, 発行日 2006-05-25 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| その他の言語のタイトル | ||||||
| その他のタイトル | Novel Microporous Iron(III) Carboxylate Polymer Complexes Containing Metalloporphyrin: Synthesis and Heterogeneous Photo-oxidation Catalysis | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学 | |||||
