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反応のタイプと発見のエピソードで学ぶ有機金属化学(11)
https://doi.org/10.24792/0002000112
https://doi.org/10.24792/0002000112450422d7-6414-41d9-af57-a196fbce922d
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
12 反応のタイプと発見のエピソードで学ぶ有機金属化学(11).pdf (2.2 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2023-09-21 | |||||
| タイトル | ||||||
| タイトル | 反応のタイプと発見のエピソードで学ぶ有機金属化学(11) | |||||
| 言語 | ja | |||||
| タイトル | ||||||
| タイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (11) | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Reppe reaction | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | cyclobutadiene complex | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | [2+2+2]cycloaddition | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | metallacyclopentadiene | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| ID登録 | ||||||
| ID登録 | 10.24792/0002000112 | |||||
| ID登録タイプ | JaLC | |||||
| 著者 |
加部, 義夫
× 加部, 義夫 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds have been known and studied since the 19 century and have been widely used to influence synthetic transformation in modern organic chemistry. It is suggested that many educational benefits could result from the use of reaction types and discoveries for undergraduates and graduate classes in organic and organometallic chemistry. Organometallic reactions are categorized into several types of metathesis reactions, depending on the combination of σ- and π-bonds, such as σ-σ bond, σ-π bond, and π-π bond metathesis. This article is organized into cycloaddition reactions and thereafter, reactions of which consist of σ-π bond metathesis, i.e., oxidative insertion of π-bond into a metallacyclopentadiene complex as an intermediate. In 1948, Ni-catalyzed cyclooligomerization of acetylene to benzene as well as cyclotetraene (COT) was first reported by Reppe of BASF. The theoretician proposed the cyclobuadiene complex to be a stable intermediate in these reactions. However subsequent studies revealed that instead of the cyclobutadiene complex, a cyclopentadiene complex is intermediate for the Reppe reaction. Cyclobutadiene and cyclopentadiene complexes will be also discussed in relation to 4 π antiaromaticity as the well as synthetic [2+2+2] cycloadiition reaction. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 教育論文 | |||||
| 言語 | ja | |||||
| 書誌情報 |
Science Journal of Kanagawa University en : Science Journal of Kanagawa University 巻 34, p. 71-83, 発行日 2023-07-30 |
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| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学総合理学研究所 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | Research Institute for Integrated Science, Kanagawa University | |||||
| 言語 | en | |||||
