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反応のタイプと発見のエピソードで学ぶ有機金属化学(6)
http://hdl.handle.net/10487/00016007
http://hdl.handle.net/10487/00016007bacf93f6-9743-4c63-a73f-13f2402fcce3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
17 反応のタイプと発見のエピソードで学ぶ有機金属化学(6) (1.7 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2020-03-19 | |||||
| タイトル | ||||||
| タイトル | 反応のタイプと発見のエピソードで学ぶ有機金属化学(6) | |||||
| 言語 | ja | |||||
| タイトル | ||||||
| タイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (6) | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | olefin complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | π-allyl | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | allylation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | phospine complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | hydrogenation | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | olefin complex | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | π-allyl complex | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | allylation | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | phospine complex | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | hydrogenation | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
加部, 義夫
× 加部, 義夫 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds have been known and studied since the 19th century and have been widely applied to influerce. synthetic transformation in modern organic chemistry. Many educational benefits could result from the use of reaction types and discovery episodes for undergraduates and graduate classes in organic and organometallic chemistry. Wilke, the successor of Ziegler and director of Max-Planck-Institute für Kohlenforschung, took over research on the Ni-effect, which brought about the discovery of the Ziegler-Natta catalyst. He discovered the TiCl4/AlEt2Cl catalyzed oligomerization reaction of butadiene to yield cyclododecatriene (CDT) without a olymer. Furthermore, the olefin and π-allyl Ni-complexes were isolated and found to act as important intermediates for oligomerization. Around the same time, the Wacker method was applied to industrial reactions in which water was added to ethylene ligand of the Pd(II) complex to give acetoaldehyde. Tsuji discovered a similar type of reaction : nucleophile addition to the π-allyl ligand of the π-ally Pd (II) complex, which was developed to Pd(0) catalyzed allylation (Tsuji –Trost reaction). On the other hand the heterogeneous Ni catalyst has been applied to the industrial hydrogenation reaction since its discovery by Sabatier. When Wilkinson modified Rh(III) (Pyridine)3Cl3 as one of the homogeneous hydrogenation catalysts with Ph3P instead of pyridine as a ligand, he serendipitously discovered the very active and coordinatively unsaturated Rh(I)(Ph3P)3Cl complex (Wilkinson catalyst). Knowles and the Monsant company applied these phosphine Rh(I) catalysts to the asymmnetric synthesis of amino acid derivatives such as L-doapa. After that, Kagen and Noyori improved phosphine ligands such as DIPHOS and BIANP, which resulted in high optical yield syntheses of amino acids from 83 to 100% enantiomer excess (ee), respectively. | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 教育論文 | |||||
| 書誌情報 |
en : Science Journal of Kanagawa University 巻 30, p. 111-118, 発行日 2019-06-30 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| その他の言語のタイトル | ||||||
| その他のタイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (6) | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学総合理学研究所 | |||||
| 資源タイプ | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Departmental Bulletin Paper | |||||
