{"created":"2023-05-15T11:46:51.030723+00:00","id":7526,"links":{},"metadata":{"_buckets":{"deposit":"e9ffc06c-bb24-4f9b-8aea-99db744ab1a5"},"_deposit":{"created_by":1,"id":"7526","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"7526"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00007526","sets":["376:377:574:584"]},"author_link":["24028","24025","24026","24027"],"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-03","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"189","bibliographicVolumeNumber":"2003","bibliographic_titles":[{"bibliographic_title":"年報"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"天然系抗菌剤のヒノキチオール(Hhino;4-イソプロピルトロボロン)を配位子とした銀(I)錯体を合成した。Hhinoのナトリウム塩[Na(hino)]・2H_2Oと硝酸銀(I)を水中でモル比1:1で反応させ、黄色の銀(I)錯体を得た(収率56.0%)。この錯体はDMSO,CHCl_3に可溶、水、アセトン、酢酸エチル、エーテルに不溶であった。溶液中で光に対して不安定であり、単結晶X線回折測定に適した結晶は得られなかった。既に構造解析されているD,L-アスパラギン酸による銀(I)の二核錯体[Ag_2(D-Hasp)(L-Hasp)]の結合距離、結合角のデータをreferenceにして、粉末X線回折データを用いたRietveld解析で構造解析を行った。この錯体はAg_2O_4をコアとしたAg-Ag結合(2.84A)もつ二核錯体[Ag(hino)]_2であった。この錯体はバクテリア、酵母、カビに対して広いスペクトルの抗菌活性を示した。抗菌性を示さないヒノキチオールコバルト(II)錯体[Co(hino)_2(EtOH)]_2やアルミニウム(III)錯体[Al(hino)_3]・MeOHの分子構造と比較して、銀-酸素結合錯体の抗菌作用を考察した。配位子hinoは銀イオンを生体系へ運搬する役割を果たしていると思われる。","subitem_description_type":"Abstract"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11822302","subitem_source_identifier_type":"NCID"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野宮, 健司"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"清水, 克也"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nomiya, Kenji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimizu, Katsuya"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"kana-1-10-0026.pdf","filesize":[{"value":"202.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kana-1-10-0026.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/7526/files/kana-1-10-0026.pdf"},"version_id":"b50c90f2-967b-42a3-8a81-3df624dbc20e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ヒノキチオール金属錯体の合成、X線構造解析および抗菌活性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ヒノキチオール金属錯体の合成、X線構造解析および抗菌活性"}]},"item_type_id":"3","owner":"1","path":["584"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-23"},"publish_date":"2009-02-23","publish_status":"0","recid":"7526","relation_version_is_last":true,"title":["ヒノキチオール金属錯体の合成、X線構造解析および抗菌活性"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T08:32:40.289966+00:00"}