{"created":"2023-05-15T11:46:48.367269+00:00","id":7465,"links":{},"metadata":{"_buckets":{"deposit":"0356d797-2c0f-4dee-bc63-b9025e44cb08"},"_deposit":{"created_by":1,"id":"7465","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"7465"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00007465","sets":["376:377:574:582"]},"author_link":["23664","23665","23666","23663"],"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-03","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"101","bibliographicVolumeNumber":"2001","bibliographic_titles":[{"bibliographic_title":"年報"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"糖はその分子内に多数のOH基を有する有機物であり,水溶液中で変旋光を示す。D-glucoseでは,水溶液中で1位のOH基の立体配置に基づくα, β異性化が起こるため,糖分子周囲の水和構造にも変化が生じると考えられる。高周波分光法は,溶液構造変化あるいは分子同士の会合状態変化を鋭敏に検出することが可能である。今回,D-glucoseのα, β異性化反応過程を高周波分光法により追跡し,1800MHz付近の共振ピークが反応時間によってその吸収強度に変化が生じることを見出した。吸収強度変化は,異性化反応時間との間に直線関係が成立し,比旋光度変化との間にも良い相関が得られた。","subitem_description_type":"Abstract"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11822302","subitem_source_identifier_type":"NCID"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"杉谷, 嘉則"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"武井, 尊也"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sugitani, Yoshinori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takei, Takaya"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"kana-1-8-0025.pdf","filesize":[{"value":"172.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kana-1-8-0025.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/7465/files/kana-1-8-0025.pdf"},"version_id":"26676918-d455-4b6c-8d89-b9db2b8ca871"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"<所内学術研究成果報告>L. 水の科学と高周波分光","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"<所内学術研究成果報告>L. 水の科学と高周波分光"}]},"item_type_id":"3","owner":"1","path":["582"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-23"},"publish_date":"2009-02-23","publish_status":"0","recid":"7465","relation_version_is_last":true,"title":["<所内学術研究成果報告>L. 水の科学と高周波分光"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T08:35:19.597725+00:00"}