{"created":"2023-05-15T11:46:44.688145+00:00","id":7380,"links":{},"metadata":{"_buckets":{"deposit":"e49233d4-6b9d-4908-82e6-c7f3c80f3f1e"},"_deposit":{"created_by":1,"id":"7380","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"7380"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00007380","sets":["376:377:574:580"]},"author_link":["23105","23101","23100","23103","23104","23102"],"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2000-03","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"47","bibliographicPageStart":"39","bibliographicVolumeNumber":"'99","bibliographic_titles":[{"bibliographic_title":"年報"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have examined the column chromatography using hydrophobic gel, Sephadex LH-20,for separation of the derivatives and isomers of the bufadienolide; bufalin, cinobufagin, and resibufogenin. The use of n-hexane/CH_2Cl_2/MeOH(4 : 5 : 1) and n-hexane/EtOAc/MeOH(4 : 5 : 1) as developing solvents provides the effective separation of the bufadienolide derivatives such as 3-ester, 3-oxo, Δ^4,and Δ^<1,4> derivatives and isomers at 14-position. By this study with previous separation for natural bufadienolides, the use of hydrophobic gel was found to be useful in the point of less-energy and economic aspect, besides the good separation.","subitem_description_type":"Abstract"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11822302","subitem_source_identifier_type":"NCID"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamashita, Ayano"}],"nameIdentifiers":[{"nameIdentifier":"23100","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nogawa, Toshihiko"}],"nameIdentifiers":[{"nameIdentifier":"23101","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamano, Yoshiaki"}],"nameIdentifiers":[{"nameIdentifier":"23102","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山下, 文乃"}],"nameIdentifiers":[{"nameIdentifier":"23103","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"野川, 俊彦"}],"nameIdentifiers":[{"nameIdentifier":"23104","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"釜野, 徳明"}],"nameIdentifiers":[{"nameIdentifier":"23105","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"kana-1-6-0008.pdf","filesize":[{"value":"1.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kana-1-6-0008.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/7380/files/kana-1-6-0008.pdf"},"version_id":"35eca0e6-9c32-4275-83df-a865a352a70f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"SIMPLE SEPARATION OF THE BUFADIENOLIDE DERIVATIVES AND ISOMERS BY THE HYDROPHOBIC GEL SEPHADEX LH-20","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"SIMPLE SEPARATION OF THE BUFADIENOLIDE DERIVATIVES AND ISOMERS BY THE HYDROPHOBIC GEL SEPHADEX LH-20"}]},"item_type_id":"3","owner":"1","path":["580"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-23"},"publish_date":"2009-02-23","publish_status":"0","recid":"7380","relation_version_is_last":true,"title":["SIMPLE SEPARATION OF THE BUFADIENOLIDE DERIVATIVES AND ISOMERS BY THE HYDROPHOBIC GEL SEPHADEX LH-20"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T08:38:47.274886+00:00"}