@article{oai:kanagawa-u.repo.nii.ac.jp:00007346, author = {野宮, 健司 and 小田, 宗宏 and Nomiya, Kenji and Oda, Munehiro}, journal = {年報}, month = {Mar}, note = {The reaction of Ni(OAc)_2 with N'-[1-(2-pyridyl) ethylidene] morpholine-4-carbothiohydrazide (HL) afforded two nickel (II) complexes, [Ni(L)_2] (1) and [Ni(L)(OAc)] (2), depending on reaction temperature and starting molar ratio; the former was a 6-coordinate, paramagnetic complex and the latter a 4-coordinate, diamagnetic complex. X-ray analysis of the complex 2 revealed that the ligands, L and OAc, were coordinated to the central metal ion to form a square-planar geometry. The complex 2 showed enhanced antimicrobial activities against selected Gram-positive bacteria, compared with those of the ligand alone, whereas the other complex 1 showed no activity.}, title = {L. チオセミカルバゾン三座配位子による金属錯体の合成と抗菌活性}, volume = {'97}, year = {1998} }