{"created":"2023-05-15T11:46:25.736803+00:00","id":6966,"links":{},"metadata":{"_buckets":{"deposit":"8f5190d8-259e-4748-81fd-1383f1fa175d"},"_deposit":{"created_by":1,"id":"6966","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"6966"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00006966","sets":["376:377:378:558"]},"author_link":["20987","20992","20984","20988","20991","20990","20986","20993","20989","20985"],"item_3_alternative_title_20":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Preparation of Acid and Oxidation Catalysts Utilizing Lacunary Sites of Polyoxometalates as Useful Chemical Reaction Field"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"70","bibliographicPageStart":"67","bibliographicVolumeNumber":"19","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Three olefin-containing organosilyl derivatives supported on the mono-lacunary\nDawson polyoxometalate (POM), [α2-P2W17O61{(RSi)2O}]6– (R = {CH2=C(CH3)COO(CH2)3}; 1,\n{CH2=CHCOO(CH2)3}; 2 and {CH2=CH}; 3), as Me2NH2 salts, which can act as precursors for\nthe immobilization of the POMs in polymer networks, were obtained by the 2:1 molar ratio\nreaction of the organosilyl precursor RSi(OCH3)3 with K10[α2-P2W17O61]·19H2O in acidic\nMeOH/H2O mixed solutions. These compounds were unequivocally characterized with\ncomplete elemental analysis, TG/DTA, FT-IR, solution (1H, 13C, 29Si, 31P, and 183W) NMR,\nand X-ray crystallography. X-ray crystallography revealed that the two organic chains\nconnected through an -Si-O-Si- bond were grafted onto the mono-lacunary site of the POM.\nThe four-coordination of each Si atom was attained with the bridging oxygen atom, the\nterminal organic group R in the organosilyl group, and two of the four oxygen atoms in the\nmono-lacunary site of the POM. In the solid-state, two POMs (1, 3) were represented as C1\nsymmetry, on the other hand, 2 could be depicted as an approximate Cs symmetry. In the\nsolution, all POMs were represented as Cs symmetry owing to mobility of the organic\nchains.","subitem_description_type":"Abstract"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"■短 報■ 2007 年度神奈川大学総合理学研究所共同研究助成論文","subitem_description_type":"Other"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野宮, 健司"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nomiya, Kenji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"力石, 紀子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Chikaraishi, Noriko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"栗嶋, 進"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kurishima, Susumu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"長谷川, 剛"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hasegawa, Takeshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"木村, 卓央"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kimura, Takao"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"12 19 67-70.pdf","filesize":[{"value":"8.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"12 19 67-70.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/6966/files/12 19 67-70.pdf"},"version_id":"942c38a6-a60f-4854-89c0-7efa5d9f1f41"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ポリ酸塩の欠損部位を新しい化学反応空間に利用したポリ酸塩ベースの触媒設計","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ポリ酸塩の欠損部位を新しい化学反応空間に利用したポリ酸塩ベースの触媒設計"}]},"item_type_id":"3","owner":"1","path":["558"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-12-21"},"publish_date":"2009-12-21","publish_status":"0","recid":"6966","relation_version_is_last":true,"title":["ポリ酸塩の欠損部位を新しい化学反応空間に利用したポリ酸塩ベースの触媒設計"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T15:44:36.660047+00:00"}