{"created":"2023-05-15T11:46:25.378784+00:00","id":6960,"links":{},"metadata":{"_buckets":{"deposit":"edd35ecf-b3a0-4252-819a-04b9e915eb10"},"_deposit":{"created_by":1,"id":"6960","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"6960"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00006960","sets":["376:377:378:558"]},"author_link":["20934","20937","20935","20936"],"item_3_alternative_title_20":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Construction of Chiral Nano-Space toward Chiral Recognition and Asymmetric Reaction"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"32","bibliographicPageStart":"27","bibliographicVolumeNumber":"19","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Synthesis of axially chiral dicarboxylic acids with a rigid and straight structure\nwas studied. The preparation of copper salt of this type of dicarboxylic acid was also\nstudied. Optically active 2,2'-dihydroxy-1,1'-binaphthalene-4,4'-dicarboxylic acid 2a was\nprepared from the corresponding bromide 3 via cyanation followed by hydrolysis although\nthe reaction proceeded in very low yield. We found that 2a could be effectively prepared\nfrom 3 via palladium complex-catalyzed vinylation followed by KMnO4 oxidation. Direct\ncarboxylation of 3 via lithiation followed by the reaction with CO2 was unsuccessful because\nof the instability of the monolithiated intermediate. The synthesis of optically active\nallene-1,3-dicarboxylic acid 9 was investigated. The optical resolution of racemic 9 via the\nquinine salt was unsuccessful due to slow decomposition, therefore, diasteromeric\nresolution of (-)-menthyl ester was investigated. A copper (II) salt of racemic\n2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylic acid 15 was prepared. X-ray\ncrystallographic analysis of the single crystal of 15-Cu (II) showed a 2D infinite sheet\nstructure, where each sheet was composed of only one of the enantiomers of 15. The\ncrystal had micropores of 4.15 Å diameter, which well corresponded to the value obtained\nfrom the micropore size distribution measurement. Because of the micropore structure,\nthe crystal showed a large surface area (BET: 642 m2g-1, Langmuire: 919 m2g-1).","subitem_description_type":"Abstract"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"■原 著■ 2007 年度神奈川大学総合理学研究所共同研究助成論文","subitem_description_type":"Other"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"木原, 伸浩"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kihara, Nobuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森, 和亮"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mori, Wasuke"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"06 19 27-32.pdf","filesize":[{"value":"3.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"06 19 27-32.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/6960/files/06 19 27-32.pdf"},"version_id":"1b97a83f-182b-453c-9970-0b238989d484"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"axially chiral dicarboxylic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"copper","subitem_subject_scheme":"Other"},{"subitem_subject":"chiral nano-space","subitem_subject_scheme":"Other"},{"subitem_subject":"open frame network","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"不斉ナノ空間の構築と不斉認識・不斉合成反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"不斉ナノ空間の構築と不斉認識・不斉合成反応"}]},"item_type_id":"3","owner":"1","path":["558"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-12-21"},"publish_date":"2009-12-21","publish_status":"0","recid":"6960","relation_version_is_last":true,"title":["不斉ナノ空間の構築と不斉認識・不斉合成反応"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T15:44:42.567262+00:00"}