{"created":"2023-05-15T11:46:22.683500+00:00","id":6900,"links":{},"metadata":{"_buckets":{"deposit":"aabe4dd5-5b65-4361-9573-bf670ffa3892"},"_deposit":{"created_by":1,"id":"6900","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"6900"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00006900","sets":["376:377:378:555"]},"author_link":["20527","20525","20526","20524"],"item_3_alternative_title_20":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Novel Microporous Metal Carboxylate Complexes-Synthesis and Heterogeneous Catalysis"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-05-25","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"56","bibliographicPageStart":"55","bibliographicVolumeNumber":"16","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Novel microporous rhodium(II) carboxylate polymer complexes having metal-loporphyrin, Rh_2[MTCPP] (M = H_2 1, Cu^<2+> 2, Ni^<2+> 3, Pd^<2+> 4) (H_2TCPP - 4,4',4'',4'''t-(21H;23H-porphine-5,10,15,20-tetrayl)tetrakis benzole acid), were synthesized and completely characterized by elemental analysis, TG/DTA, magnetic susceptibilities, FT-IR, DR-UV-vis, XRPD, BET analysis, and nitrogen adsorption measurements. These complexes possess carboxylate bridged dinuclear rhodium(II) sites and mononuclear copper(II), nickel(II), and palladium(II) centers in the porphyrin ring to form uniform micropores of ca. 5.0 Å. Furthermore, they show high surface areas and high nitrogen adsorption capacities, and act as efficient heterogeneous catalysts for hydrogenation of olefins at approximately 200 K. The unique bimetallic effects shown by metalloporphyrin and dinuclear rhodium sites in micropores were investigated by kinetic studies and hydrogen and propene adsorption-desorption measurements; the priority coordination of olefins onto metalloporphyrins and the intramolecular transfer of hydrogen from rhodium center to the olefin molecule coordinated onto metalloporphyrin remarkably reflects the catalytic activities in hydrogenation.","subitem_description_type":"Abstract"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"森, 和亮"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"加藤, 知香"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mori, Wasuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kato, Chika"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"SJKU Vol 16 2005 55-56.pdf","filesize":[{"value":"465.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SJKU Vol 16 2005 55-56.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/6900/files/SJKU Vol 16 2005 55-56.pdf"},"version_id":"4c5ddc34-2476-446b-a51f-8bf157d93c1a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"rhodium carboxylate polymer complex","subitem_subject_scheme":"Other"},{"subitem_subject":"metalloporphyrin","subitem_subject_scheme":"Other"},{"subitem_subject":"microporous materials","subitem_subject_scheme":"Other"},{"subitem_subject":"olefin hydrogenation","subitem_subject_scheme":"Other"},{"subitem_subject":"adsorption property","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ナノ細孔をもつ光・酸化および水素化触媒の構築と地球環境改善への展開(2004年度神奈川大学総合理学研究所共同研究助成論文)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ナノ細孔をもつ光・酸化および水素化触媒の構築と地球環境改善への展開(2004年度神奈川大学総合理学研究所共同研究助成論文)"}]},"item_type_id":"3","owner":"1","path":["555"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-23"},"publish_date":"2009-02-23","publish_status":"0","recid":"6900","relation_version_is_last":true,"title":["ナノ細孔をもつ光・酸化および水素化触媒の構築と地球環境改善への展開(2004年度神奈川大学総合理学研究所共同研究助成論文)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T15:45:54.754308+00:00"}