{"created":"2023-05-15T11:43:17.808393+00:00","id":2953,"links":{},"metadata":{"_buckets":{"deposit":"feecde46-12d0-4849-8e3f-3848be34349f"},"_deposit":{"created_by":1,"id":"2953","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"2953"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00002953","sets":["237:238:239"]},"author_link":["5989","5994","5991","5993","5990","5992"],"item_7_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1993","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"1165","bibliographicPageStart":"1156","bibliographicVolumeNumber":"66","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_7_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Various kinds of nonbranched and methyl-branched 6-deoxyhex-5-enopyranoside derivatives were prepared from 6-bromo-6-deoxy or 6-O-p-tolylsulfonylhexopyranoside in a one-pot procedure by a successive treatment with iodide anion and 1,8-diazabicyclo[5.4.0]undec-7-ene in dimethyl sulfoxide. The scope and limitations of this reaction have become apparent by observing the reactions of 18 substrates. The yields of altropyranoside and 2-deoxyribo-hexopyranoside derivatives were high, except for the 2,3-anhydropyranoside derivative. Methyl-branched 6-deoxyhex-5-enopyranoside derivatives were also obtained in practical yields.","subitem_description_type":"Abstract"}]},"item_7_description_40":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_7_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会"}]},"item_7_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.66.1156","subitem_relation_type_select":"DOI"}}]},"item_7_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_7_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_7_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐藤, 憲一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sato, Ken-ichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kubo, Noriyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takada, Ritsuko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"佐久間, 詔悟"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakuma, Shogo"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-16"}],"displaytype":"detail","filename":"佐藤・化学-019.pdf","filesize":[{"value":"7.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"佐藤・化学-019.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/2953/files/佐藤・化学-019.pdf"},"version_id":"ec179e80-3b28-4630-8b06-5904d4a2b2be"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Syntheses of 6-Deoxyhex-5-enopyranosides from 6-Bromo-6-deoxy- or 6-O-p-Tolylsulfonylhexopyranosides by the Use of DBU in DMSO","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Syntheses of 6-Deoxyhex-5-enopyranosides from 6-Bromo-6-deoxy- or 6-O-p-Tolylsulfonylhexopyranosides by the Use of DBU in DMSO"}]},"item_type_id":"7","owner":"1","path":["239"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-01-28"},"publish_date":"2011-01-28","publish_status":"0","recid":"2953","relation_version_is_last":true,"title":["Syntheses of 6-Deoxyhex-5-enopyranosides from 6-Bromo-6-deoxy- or 6-O-p-Tolylsulfonylhexopyranosides by the Use of DBU in DMSO"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T16:34:59.516737+00:00"}