{"created":"2023-05-15T11:43:17.181053+00:00","id":2939,"links":{},"metadata":{"_buckets":{"deposit":"8fd010ac-2881-4c0c-8604-ca8c5fd2fd0f"},"_deposit":{"created_by":1,"id":"2939","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"2939"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00002939","sets":["237:238:239"]},"author_link":["5903","5905","5902","5899","5904","5900","5901"],"item_7_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1976-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1689","bibliographicPageStart":"1686","bibliographicVolumeNumber":"49","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_7_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Stereoselectivities in the Grignard, diazomethane and nitromethane reaction of methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose (1) were examined. In contrast to the Grignard reaction of 1 using methylmagnesium iodide to give a single 2-C-methyl derivative (4), the diazomethane reaction followed by reduction afforded another epimer (6). The nitromethan condensation product (10) of 1 was converted into the corresponding 2-C-acetaminomethyl derivative (13). The NMR spectrum of 2-O-acetate of 4 and comparison of the optical rotations of 4, 6, 10 and 13 in cupraramonium solution indicated that 4 and others have D-gluco-and D-manno-configuration, respectively. Discussions were made on the stereoselectivties of these reactions.","subitem_description_type":"Abstract"}]},"item_7_description_40":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_7_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会"}]},"item_7_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.49.1686","subitem_relation_type_select":"DOI"}}]},"item_7_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_7_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"吉村, 寿次"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshimura, Juji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mikami, Kazutoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"佐藤, 憲一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sato, Ken-ichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"辛, 重基"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shin, Chung-gi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-16"}],"displaytype":"detail","filename":"佐藤・化学-005.pdf","filesize":[{"value":"3.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"佐藤・化学-005.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/2939/files/佐藤・化学-005.pdf"},"version_id":"a68d837e-c9f8-4590-bac0-5c33e05e865d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Branched-chain Sugars. VIII. On the Configuration of Branched-chain Sugars from Methyl 3-O-Benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Branched-chain Sugars. VIII. On the Configuration of Branched-chain Sugars from Methyl 3-O-Benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose"}]},"item_type_id":"7","owner":"1","path":["239"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-01-28"},"publish_date":"2011-01-28","publish_status":"0","recid":"2939","relation_version_is_last":true,"title":["Branched-chain Sugars. VIII. On the Configuration of Branched-chain Sugars from Methyl 3-O-Benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T16:35:09.918979+00:00"}