{"created":"2023-05-15T11:43:17.000991+00:00","id":2935,"links":{},"metadata":{"_buckets":{"deposit":"c9531531-1216-4c15-91d7-5e16c745d9a4"},"_deposit":{"created_by":1,"id":"2935","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"2935"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00002935","sets":["237:238:239"]},"author_link":["5870","5873","5872","5871","5874","5876","5875"],"item_7_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1972-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1812","bibliographicPageStart":"1806","bibliographicVolumeNumber":"45","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_7_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to obtain a 3-C-hydroxymethyl-D-glucose derivative some nucleophilic reactions of 1,2 : 5,6-di-O-isopropylidene-α-D-ribo-hexofuranos-3-ulose (1) and the configurations of products have been examined. Gluco-and allo-configurations of known 3-C-nitromethyl derivatives of 1 were confirmed by the fact that 3-C-acetaminomethyl-1,2-O-isopropylidene-α-D-xylo- and ribo-pentodialdofuranoses, derived by four successive transformations, showed the absence and presence of the aminal-ring formation between the aldehyde and acetamino groups, respectively. A 3-C-carbethoxymethyl derivative obtained by the Reformatsky reaction of 1 with ethyl bromoacetate was proved to be of allo-configuration by the lactone-formation between C5-hydroxyl and carboxyl groups. The configuration of 3-C-hydroxymethyl derivative (15) obtained by treatment of known 3-C-methylene derivative of 1 with permanganate was proved to be of gluco-typc by comparison of the corresponding 3-C-aminomethyl derivative (5), derived by three-step conversions, with that obtained from 3-C-nitromethyl derivatives. 15 was also obtained by epoxidation of 1 with diazomethane followed by ring-opening with alkali. Treatment of 5 and its allo-epimer with nitrous acid gave, respectively, a ring-expanded product and the 3′,5-anhydride, the former being also recognized in the epoxidation products. Structures of new compounds were examined by NMR spectra and stereoselectivity of reactions discussed.","subitem_description_type":"Abstract"}]},"item_7_description_40":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_7_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会"}]},"item_7_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.45.1806","subitem_relation_type_select":"DOI"}}]},"item_7_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_7_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_7_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"吉村, 寿次"}],"nameIdentifiers":[{"nameIdentifier":"5870","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yoshimura, Juji"}],"nameIdentifiers":[{"nameIdentifier":"5871","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kobayashi, Kazuhiko"}],"nameIdentifiers":[{"nameIdentifier":"5872","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"佐藤, 憲一"}],"nameIdentifiers":[{"nameIdentifier":"5873","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sato, Ken-ichi"}],"nameIdentifiers":[{"nameIdentifier":"5874","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"舟橋, 弥益男"}],"nameIdentifiers":[{"nameIdentifier":"5875","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Funabashi, Masuo"}],"nameIdentifiers":[{"nameIdentifier":"5876","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-16"}],"displaytype":"detail","filename":"佐藤・化学-001.pdf","filesize":[{"value":"4.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"佐藤・化学-001.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/2935/files/佐藤・化学-001.pdf"},"version_id":"48c2eec8-fcec-4e1a-add8-8c2ddf6a5504"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Branched-Chain Sugars. I. On the Configuration of Branched-Chain Derivatives of 1,2 : 5,6-Di-O-isopropylidene-α-D-ribo-hexofuranos-3-ulose","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Branched-Chain Sugars. I. On the Configuration of Branched-Chain Derivatives of 1,2 : 5,6-Di-O-isopropylidene-α-D-ribo-hexofuranos-3-ulose"}]},"item_type_id":"7","owner":"1","path":["239"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-01-28"},"publish_date":"2011-01-28","publish_status":"0","recid":"2935","relation_version_is_last":true,"title":["Branched-Chain Sugars. I. On the Configuration of Branched-Chain Derivatives of 1,2 : 5,6-Di-O-isopropylidene-α-D-ribo-hexofuranos-3-ulose"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T16:35:12.745805+00:00"}