{"created":"2023-05-15T11:43:16.956391+00:00","id":2934,"links":{},"metadata":{"_buckets":{"deposit":"22c6575f-cf6f-47fe-abe7-991e13c6bd45"},"_deposit":{"created_by":1,"id":"2934","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"2934"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00002934","sets":["237:238:239"]},"author_link":["5866","5867","5869","5868"],"item_7_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1995","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"83","bibliographicPageStart":"83","bibliographicVolumeNumber":"24","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters"}]}]},"item_7_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reactions of methyl 4,6-O-benzylidene-2-O-benzoyl- and -2-O-methyl-α-D-ribo-hexopyranosid-3-ulose with dichloromethyllithium gave the corresponding α-hydroxydichloromethyl derivatives in 75% and 87% yields, respectively. The structures of these products were determined by derivation into known compounds, respectively. A novel reaction of dichloromethyl derivatives with cesium acetate was found to give 3-α-hydroxyaldehyde or 3-α-acetoxyaldehyde derivative as a main product. SN2 inversion via spirochloroepoxide was suggested in this reaction by determining configuration of each product.","subitem_description_type":"Abstract"}]},"item_7_description_40":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_7_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会"}]},"item_7_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/cl.1995.83","subitem_relation_type_select":"DOI"}}]},"item_7_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0366-7022","subitem_source_identifier_type":"ISSN"}]},"item_7_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐藤, 憲一"}],"nameIdentifiers":[{"nameIdentifier":"5866","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sato, Ken-ichi"}],"nameIdentifiers":[{"nameIdentifier":"5867","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Katsuhiko"}],"nameIdentifiers":[{"nameIdentifier":"5868","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hashimoto, Yoshihisa"}],"nameIdentifiers":[{"nameIdentifier":"5869","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-16"}],"displaytype":"detail","filename":"佐藤・化学-39.pdf","filesize":[{"value":"705.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"佐藤・化学-39.pdf","url":"https://kanagawa-u.repo.nii.ac.jp/record/2934/files/佐藤・化学-39.pdf"},"version_id":"a9f39f98-e01a-4969-ae6f-ed0cadef20f2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reaction of α-Hydroxydichloromethyl Derivatives with Cesium Acetate","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reaction of α-Hydroxydichloromethyl Derivatives with Cesium Acetate"}]},"item_type_id":"7","owner":"1","path":["239"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-01-27"},"publish_date":"2011-01-27","publish_status":"0","recid":"2934","relation_version_is_last":true,"title":["Reaction of α-Hydroxydichloromethyl Derivatives with Cesium Acetate"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T16:35:13.892998+00:00"}