{"created":"2023-09-21T04:04:24.820594+00:00","id":2000117,"links":{},"metadata":{"_buckets":{"deposit":"9355d4d2-2df1-44cf-9d8f-0301809f849b"},"_deposit":{"created_by":10,"id":"2000117","owner":"10","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"2000117"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:02000117","sets":["376:377:378:1694564780134"]},"author_link":["34291","34291"],"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-07-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"23","bibliographicPageStart":"19","bibliographicVolumeNumber":"34","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University"},{"bibliographic_title":"Science Journal of Kanagawa University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"This study focused on dissolution and solvation of CO2 in ionic liquids to understand the mechanism of its highly soluble nature in ionic liquids. We considered that the internal structure of the void in ionic liquids accommodates small gas molecules such as CO2 and O2. To understand the voids, time-resolved near infrared spectroscopy of singlet oxygen was performed in ionic liquids. Regarding peak shift values of singlet oxygen phosphorescence from that in the gas phase, the size of voids in ionic liquids was estimated. Even in the presence of a large amount of dissolved CO2 in ionic liquids, no further spectral shift of singlet oxygen was observed. This spectroscopic information suggests that no voids are occupied by coexisting CO2 and O2 molecules. Voids are rather occupied with either CO2 or O2 and, therefore, spectral shift of singlet oxygen does not occur. This model was well rationalized by estimation of the dissolved CO2 concentration using reported Henry constant values of CO2 in ionic liquids. We considered that a much higher concentration of CO2 under higher pressure of CO2 in the order of 10 atm will cause unusual spectral shifts of singlet oxygen.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"原著　2022年度神奈川大学総合理学研究所共同研究助成論文","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24792/0002000117","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学総合理学研究所","subitem_publisher_language":"ja"},{"subitem_publisher":"Research Institute for Integrated Science, Kanagawa University","subitem_publisher_language":"en"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"PISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"渡邉, 諒","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"田村, 麻美","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"吉田, 剛","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"河合, 明雄","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"34291","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"34291","nameIdentifierScheme":"ローカル著者ID"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-09-21"}],"filename":"04 一重項酸素りん光の近赤外分光計測を利用したイオン液体中の二酸化炭素吸着機構の解明.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kanagawa-u.repo.nii.ac.jp/record/2000117/files/04 一重項酸素りん光の近赤外分光計測を利用したイオン液体中の二酸化炭素吸着機構の解明.pdf"},"version_id":"714ce36d-b6b7-4b9e-98ff-eb042c8ad8c8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"time-resolved near IR spectroscopy","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"singlet oxygen","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ionic liquid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"carbon dioxide spectral shift","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"solvation","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"一重項酸素りん光の近赤外分光計測を利用したイオン液体中の二酸化炭素吸着機構の解明","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"一重項酸素りん光の近赤外分光計測を利用したイオン液体中の二酸化炭素吸着機構の解明","subitem_title_language":"ja"},{"subitem_title":"Dissolution and Solvation Nature of Carbon Dioxide in Ionic Liquids as Studied by Time-Resolved Near Infrared Spectroscopy for Singlet Oxygen Phosphorescence","subitem_title_language":"en"}]},"item_type_id":"3","owner":"10","path":["1694564780134"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-09-21"},"publish_date":"2023-09-21","publish_status":"0","recid":"2000117","relation_version_is_last":true,"title":["一重項酸素りん光の近赤外分光計測を利用したイオン液体中の二酸化炭素吸着機構の解明"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-10-11T00:15:26.521077+00:00"}