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反応のタイプと発見のエピソードで学ぶ有機金属化学(10)
http://hdl.handle.net/10487/00018162
http://hdl.handle.net/10487/00018162cbe65963-7d40-47e3-a364-51456ed46fa2
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
16 反応のタイプと発見のエピソードで学ぶ有機金属化学(10) (1.2 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2022-09-21 | |||||
| タイトル | ||||||
| タイトル | 反応のタイプと発見のエピソードで学ぶ有機金属化学(10) | |||||
| 言語 | ja | |||||
| タイトル | ||||||
| タイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (10) | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | C-H activation σ-bond metahesis | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | oxidative addition | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | C-H activation σ-bond metahesis | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | oxidative addition | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
加部, 義夫
× 加部, 義夫 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds have been known and studied since the 19th century and have been widely used to influence synthetic transformation in modern organic chemistry. It is considered that many educational benefits could result from the use of reaction types and discoveries for undergraduates and graduates of organic and organometallic chemistry. Organometallic reactions were categorized into several types of metathesis reaction, depending on the combination of σ- and π-bonds, such as σ-σ bond , σ-π bond and π-π bond metathesis. This article is organized into C-H and C-C-bond activation, which consists of traditional oxidative addition mechanisms and σ-σ bond metathesis using either early- or late transition metals. The first example of late transition metal-mediated C-H activation was reported by Chatt and Davidson in 1965, in which naphthalene was found to form Ru(0) complexes and undergo C-H activation to give an Ru(II) hydride/alkyl product via an oxidative addition mechanism. On the other hand, Watson and Pharshall at Dupont Company for the first time reported that an early transition metal catalyzed methane exchange at Cp*2LuMe via a four-centered σ-bond metathesis mechanism. New mechanisms such as 1,2-addition as well as an σ-complex-assisted mechanism (σ-CAM) were also described. The remaining σ-π and π-π bond metathesis such as cycloaddition, olefin metathesis, and olefin polymerization will be discussed the next time in the final article of this series. | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 教育論文 | |||||
| 書誌情報 |
en : Science Journal of Kanagawa University 巻 33, p. 115-124, 発行日 2022-07-30 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1880-0483 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12068302 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | 神奈川大学総合理学研究所 | |||||
| 出版者 | ||||||
| 出版者 | Research Institute for Integrated Science, Kanagawa University | |||||
