{"created":"2023-05-15T11:52:42.561649+00:00","id":15087,"links":{},"metadata":{"_buckets":{"deposit":"21d632dc-3896-4e81-a6af-0567b688dd81"},"_deposit":{"created_by":10,"id":"15087","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"15087"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00015087","sets":["376:377:378:1428"]},"author_link":["37167","37168","37169","37170","35218","37172","37173","37174","37175","35218"],"control_number":"15087","item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-07-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"52","bibliographicPageStart":"47","bibliographicVolumeNumber":"33","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Thiolate iron complexes with a phenanthridine moiety were synthesized from 4-(benzo[b ]thiophen-2-yl)phenanthridine. The photoreaction of pentacarbonyl iron with the ligand precursor afforded the diiron carbonyl complex [Fe2(L3)(CO)5], where L3 is a dianionic N,C,S-tridentate ligand containing thiolate S, vinyl C, and phenanthridine N. The diiron complex was converted to the N,C,S-pincer iron(II) complex trans -[Fe(L3)(CO)(PMe3)2] by reaction with an excess amount of trimethylphosphine. The electronic absorption spectrum of trans-[Fe(L3)(CO)(PMe3)2] was compared with those of the analogous iron(II) complexes trans-[Fe(L1)(CO)(PMe3)2] and trans -[Fe(L2)(CO)(PMe3)2], where L1 contains thiolate S, phenyl C, and pyridine N, and L2 contains thiolate S, vinyl C, and quinoline N. For trans-[Fe(L3)(CO)(PMe3)2], an intense band was observed at around 500 nm, which is due to the transition from the orbitals around the thiolate-containing metallacycle to phenanthridine moiety. The corresponding absorption band of trans -[Fe(L2)(CO)(PMe3)2] appears in a similar region at a lower intensity.  These bands are red-shifted compared with trans -[Fe(L1)(CO)(PMe3)2], which is attributed to the π systems containing the vinyl moiety. The higher intensity and red-shift for the phenanthridine-based iron(II) complex are consistent with the TD-DFT calculations of these three N,C,S-pincer iron(II) complexes.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"原著\n2021年度神奈川大学総合理学研究所共同研究助成論文","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24792/0000015087","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学総合理学研究所","subitem_publisher_language":"ja"},{"subitem_publisher":"Research Institute for Integrated Science, Kanagawa University","subitem_publisher_language":"en"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"PISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"塩谷, 直樹","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"37167","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"藤井, 翔","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"37168","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊藤, 亮孝","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"37169","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中島, 洋","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"37170","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"廣津, 昌和","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"35218","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"35218","nameIdentifierScheme":"ローカル著者ID"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-09-20"}],"displaytype":"detail","filename":"06 フェナントリジン部位をもつN,C,S-ピンサー鉄錯体の合成と分光学的性質.pdf","filesize":[{"value":"1.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"06 フェナントリジン部位をもつN,C,S-ピンサー鉄錯体の合成と分光学的性質","url":"https://kanagawa-u.repo.nii.ac.jp/record/15087/files/06 フェナントリジン部位をもつN,C,S-ピンサー鉄錯体の合成と分光学的性質.pdf"},"version_id":"c235eb5e-fd4c-474b-bb35-b66d79b3ac16"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"iron complex","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"benzothiophene derivatives","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"N,C,S-tridentate ligand","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"phenanthridine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"charge transfer transition","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"electronic spectrum","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"フェナントリジン部位をもつN,C,S-ピンサー鉄錯体の合成と分光学的性質","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"フェナントリジン部位をもつN,C,S-ピンサー鉄錯体の合成と分光学的性質","subitem_title_language":"ja"},{"subitem_title":"Synthesis and Spectroscopic Properties of N,C,S-Pincer Iron Complexes Bearing a Phenanthridine Moiety","subitem_title_language":"en"}]},"item_type_id":"3","owner":"10","path":["1428"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-09-20"},"publish_date":"2022-09-20","publish_status":"0","recid":"15087","relation_version_is_last":true,"title":["フェナントリジン部位をもつN,C,S-ピンサー鉄錯体の合成と分光学的性質"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-08-08T06:42:37.539081+00:00"}