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反応のタイプと発見のエピソードで学ぶ有機金属化学(4)
http://hdl.handle.net/10487/00015649
http://hdl.handle.net/10487/00015649602cc4a6-d8c1-47f4-93da-9cc9156da780
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
19 反応のタイプと発見のエピソードで学ぶ有機金属化学(4) (993.3 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||
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| 公開日 | 2019-06-07 | |||||||
| タイトル | ||||||||
| タイトル | 反応のタイプと発見のエピソードで学ぶ有機金属化学(4) | |||||||
| 言語 | ja | |||||||
| タイトル | ||||||||
| タイトル | Organometallic Chemistry Based on Reaction Types and Anecdotes of Discoveries (4) | |||||||
| 言語 | en | |||||||
| 言語 | ||||||||
| 言語 | jpn | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | transition metal compounds | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | metal carbonyls | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | metallocene | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | ferrocene | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | departmental bulletin paper | |||||||
| 著者 |
加部, 義夫
× 加部, 義夫
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| 抄録 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds have been known and studied since the 19 century and have been widely used for synthetic transformation in modern organic chemistry. Their many educational benefits could result in the use of reaction types and discoveries in undergraduate and graduate classes in organic and organometallic chemistry. As the latter half of this approach, this report deals with transition metals. Mond was a chemist and entrepreneur with an alkali soda business. To improve the synthesis of alkali soda, i.e., the solvey method, he discovered binary gaseous metal carbonyls Ni(CO)4, with the same toxicity as KCN. The metal carbonyls were applied to industrial reactions such as the hydroformylation (Oxo or Roelen syntheses) of olefins using Co2(CO)8 and Reppe synthesis of acrylic acid using Ni(CO)4 and acetylene. In the chemistry of metal carbonyls, Reppe found that Ni-catalyzed acetylene oligomerization to yield benzene and cyclotetraene (COT). First, metal carbene complexes were synthesized by Fischer as derivatives of metal carbonyls. Wilkinson tried to isolate alkyl transition metal intermediates for Ziegler-Natta polymerization but, did not succeed because of the β-H elimination reaction. Therefore, he identified Pauson’s incorrect structure of biscyclopentadienyliron. He collaborated with Woodward to report the first sandwich structure of ferrocene (Cp2Fe). Fischer also independently identified the same structure. This discovery of ferrocene (Cp2Fe) expanded metallocene chemistry. | |||||||
| 言語 | en | |||||||
| 内容記述 | ||||||||
| 内容記述タイプ | Other | |||||||
| 内容記述 | 教育論文 | |||||||
| 言語 | ja | |||||||
| 書誌情報 |
en : Science Journal of Kanagawa University 巻 29, p. 107-111, 発行日 2018-06-30 |
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| ISSN | ||||||||
| 収録物識別子タイプ | PISSN | |||||||
| 収録物識別子 | 1880-0483 | |||||||
| 書誌レコードID | ||||||||
| 収録物識別子タイプ | NCID | |||||||
| 収録物識別子 | AA12068302 | |||||||
| 著者版フラグ | ||||||||
| 出版タイプ | VoR | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| その他の言語のタイトル | ||||||||
| その他のタイトル | Organometallic Chemistry Based on Reaction Types and Anecdotes of Discoveries (4) | |||||||
| 出版者 | ||||||||
| 出版者 | 神奈川大学総合理学研究所 | |||||||
| 言語 | ja | |||||||
| 出版者 | ||||||||
| 出版者 | Research Institute for Integrated Science, Kanagawa University | |||||||
| 言語 | en | |||||||
