{"created":"2023-05-15T11:50:45.949766+00:00","id":12532,"links":{},"metadata":{"_buckets":{"deposit":"18bda13a-e09a-4d33-b674-2d134ea632d7"},"_deposit":{"created_by":10,"id":"12532","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"12532"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00012532","sets":["376:377:378:1219"]},"author_link":[],"item_3_alternative_title_20":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Experimental and Theoretical Studies on Conformationally Controlled Oligosilanes"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"53","bibliographicPageStart":"51","bibliographicVolumeNumber":"29","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Theoretical calculations have been performed on the pentasilane compound that is conformationally constrained into all anti conformations. Optimized geometry in the photoexcited state suggests that the σσ* character is the lowest excited state in terms of the extended terminal Si-Si bonds. Meanwhile, the bond and dihedral angles are barely changed, because of the rigidity of the trisilane unit. These phenomena effectively explain the experimental data of the photophysical properties of the all anti-pentasilane compound.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"原著","subitem_description_language":"ja","subitem_description_type":"Other"},{"subitem_description":"2017年度神奈川大学総合理学研究所共同研究助成論文","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学総合理学研究所","subitem_publisher_language":"ja"},{"subitem_publisher":"Research Institute for Integrated Science, Kanagawa University","subitem_publisher_language":"en"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"PISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"辻, 勇人","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"金澤, 悠紀","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"江原, 雅博","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorNameLang":"ja"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-30"}],"displaytype":"detail","filename":"09 立体構造が制御されたオリゴシランの実験的・理論的研究.pdf","filesize":[{"value":"930.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"09 立体構造が制御されたオリゴシランの実験的・理論的研究","url":"https://kanagawa-u.repo.nii.ac.jp/record/12532/files/09 立体構造が制御されたオリゴシランの実験的・理論的研究.pdf"},"version_id":"c8ed177b-d697-469a-9324-a96b61fb34d5"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"oligosilanes","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"conformation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"photophysical properties","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"excited state","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"立体構造が制御されたオリゴシランの実験的・理論的研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"立体構造が制御されたオリゴシランの実験的・理論的研究","subitem_title_language":"ja"},{"subitem_title":"Experimental and Theoretical Studies on Conformationally Controlled Oligosilanes","subitem_title_language":"en"}]},"item_type_id":"3","owner":"10","path":["1219"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-06-07"},"publish_date":"2019-06-07","publish_status":"0","recid":"12532","relation_version_is_last":true,"title":["立体構造が制御されたオリゴシランの実験的・理論的研究"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-12-11T06:47:37.801357+00:00"}