{"created":"2023-05-15T11:50:45.906996+00:00","id":12531,"links":{},"metadata":{"_buckets":{"deposit":"ec855b97-7aae-476d-a8d8-1e2eda32e95d"},"_deposit":{"created_by":10,"id":"12531","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"12531"},"status":"published"},"_oai":{"id":"oai:kanagawa-u.repo.nii.ac.jp:00012531","sets":["376:377:378:1219"]},"author_link":[],"item_3_alternative_title_20":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Geometrical Isomer of Open-Dawson Polyoxometalate"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"50","bibliographicPageStart":"47","bibliographicVolumeNumber":"29","bibliographic_titles":[{"bibliographic_title":"Science Journal of Kanagawa University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"By the reaction of β-Keggin-type polyoxometalate (POM), [A-β-SiW9O34]10- with Fe3+ at pH 3, the β, β-isomer of open-Dawson POM containing the tetra-iron(III) cluster [{Fe4(OH2) (OH)5}(β, β-Si2W18O66)]9- (β, β-Fe4-open) was successfully synthesized as potassium salt and the molecular structure was determined. It was unequivocally characterized by complete elemental analysis, thermogravimetric and differential thermal analysis (TG/DTA), FTIR and UV-vis absorption spectroscopy, cyclic voltammetry, and X-ray crystallography. X-ray crystallography revealed that the {Fe4(H2O)(OH)5}7+ cluster ion was embedded in the open pocket moiety of the β, β-type open-Dawson POM [β, β-Si2W18O66]16- formed by the fusion of two tri-lacunary β -Keggin POMs, [A-β-SiW9O34]10-, via two W-O-W bonds. The β, β-open-Dawson POM corresponds to an opened structure of the usual γ-Dawson POM. β, β-Fe4-open is the first example of the geometrical isomer of the previously reported α, α-open-Dawson POM containing the tetra-iron(III) cluster [{Fe4(OH)6}(α, α-Si2W18O66)]10- (α, α-Fe4-open).","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"原著","subitem_description_language":"ja","subitem_description_type":"Other"},{"subitem_description":"2017年度神奈川大学総合理学研究所共同研究助成論文","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"神奈川大学総合理学研究所","subitem_publisher_language":"ja"},{"subitem_publisher":"Research Institute for Integrated Science, Kanagawa University","subitem_publisher_language":"en"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12068302","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-0483","subitem_source_identifier_type":"PISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野宮, 健司","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"井上, 雄介","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"三原, 航平","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"宮前, 枝里子","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"新井, 裕喜","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"力石, 紀子","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"松永, 諭","creatorNameLang":"ja"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-30"}],"displaytype":"detail","filename":"08 Open-Dawson 型ポリオキソメタレートの構造異性体.pdf","filesize":[{"value":"1.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"08 Open-Dawson 型ポリオキソメタレートの構造異性体","url":"https://kanagawa-u.repo.nii.ac.jp/record/12531/files/08 Open-Dawson 型ポリオキソメタレートの構造異性体.pdf"},"version_id":"f2969b0e-76f3-42d6-92fd-ceef1736a31d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"polyoxometalate","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"open-Dawson structure","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"iron","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"geometrical isomer","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Open-Dawson型ポリオキソメタレートの構造異性体","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Open-Dawson型ポリオキソメタレートの構造異性体","subitem_title_language":"ja"},{"subitem_title":"Geometrical Isomer of Open-Dawson Polyoxometalate","subitem_title_language":"en"}]},"item_type_id":"3","owner":"10","path":["1219"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-06-07"},"publish_date":"2019-06-07","publish_status":"0","recid":"12531","relation_version_is_last":true,"title":["Open-Dawson型ポリオキソメタレートの構造異性体"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-12-11T06:47:33.685605+00:00"}