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A Novel Method for Constructing β-D-Mannosidic, 2-Acetamido-2-deoxy-β-D-mannosidic, and 2-Deoxy-D-arabino-hexopyranosidic Units from the Bis(triflate) Derivative of β-D-Galactoside
http://hdl.handle.net/10487/8183
http://hdl.handle.net/10487/8183cec041a6-addd-478d-897f-77096fc7bfc5
名前 / ファイル | ライセンス | アクション |
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佐藤・化学-022.pdf (4.5 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-01-28 | |||||
タイトル | ||||||
タイトル | A Novel Method for Constructing β-D-Mannosidic, 2-Acetamido-2-deoxy-β-D-mannosidic, and 2-Deoxy-D-arabino-hexopyranosidic Units from the Bis(triflate) Derivative of β-D-Galactoside | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
佐藤, 憲一
× 佐藤, 憲一× Sato, Ken-ichi× Yoshitomo, Akira× Takai, Yoshimitsu |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | An efficient construction of the β-D-mannosidic, 2-Acetamido-2-deoxy-β-D-mannosidic, 2-deoxy-2-fluoro-β-D-mannosidic, and 2-deoxy-β-D-arabino-hexopyranosidic units from the same intermediate, 2-4-bis(O-trifluoromethylsulfonyl) derivative of β-D-galactoside, was achieved in good yields in a stepwise inversion at C-4 and C-2 by using cesium acetate, n-Bu4NN3, n-Bu4NF, and n-Bu4NBH4. A convenient and practical protection of β-D-mannoside to the straightforward synthesis of antennary oligosaccharides was also achieved by using cesium trifluoroacetate. | |||||
書誌情報 |
Bulletin of the Chemical Society of Japan 巻 70, 号 4, p. 885-890, 発行日 1997 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2673 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00580132 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/bcsj.70.885 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 日本化学会 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |