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Synthesis of the Functionalized Cyclohexanecarbaldehyde Derivative. A Potential Key Compound for Total Synthesis of Optically Active Tetrodotoxin
http://hdl.handle.net/10487/8155
http://hdl.handle.net/10487/815527b0d877-7523-4ac9-84ea-94f924c385d2
名前 / ファイル | ライセンス | アクション |
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佐藤・化学-34.pdf (1.6 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-01-27 | |||||
タイトル | ||||||
タイトル | Synthesis of the Functionalized Cyclohexanecarbaldehyde Derivative. A Potential Key Compound for Total Synthesis of Optically Active Tetrodotoxin | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
佐藤, 憲一
× 佐藤, 憲一× Sato, Ken-ichi× Kajihara, Yasuhiro× Nakamura, Yutaka× Yoshimura, Juji |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Oxidation of 1L-(1,2,3′,4,5/3,6)-3-hydroxymethyl-2,4,5-tri-O-methoxymethyl-3,3′-O-methylene-6-nitro-2,3,4,5-tetrahydroxycyclohexanecarbaldehyde dimethyl acetal with potassium t-butoxide and m-chloroperbenzoic acid has given corresponding carbonyl derivative in 65% yield. The carbonyl compound has been successfully converted into the desired key compound for tetrodotoxin synthesis in excellent yield via the spiro α-chloro-epoxide derivative. | |||||
書誌情報 |
Chemistry Letters 巻 20, 号 9, p. 1559-1562, 発行日 1991 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0366-7022 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/cl.1991.1559 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 日本化学会 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |