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反応のタイプと発見のエピソードで学ぶ有機金属化学(7)
http://hdl.handle.net/10487/00016666
http://hdl.handle.net/10487/00016666cf545f60-5fe9-4e6c-a831-f64df82c4cf9
名前 / ファイル | ライセンス | アクション |
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15 反応のタイプと発見のエピソードで学ぶ有機金属化学(7) (1.6 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2021-01-12 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | 反応のタイプと発見のエピソードで学ぶ有機金属化学(7) | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (7) | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | oxygen | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | peroxide | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | oxo-metal complex | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | peroxometal complex | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
加部, 義夫
× 加部, 義夫 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds have been known and studied since 19th century and have been widely used to effect synthetic transformation in modern organic chemistry. It seemed that many educational benefits could result in the use of reaction types and discovery episodes for undergraduate and graduate classes in organic and organometallic chemistry. The former half of this report deals with O2 and the related chemistry, the latter half deals with transition metal peroxo- and oxo- complexes. The dangerously explosive properties of hydroperoxide disturbed the development of O2 chemistry, which is primarily a product of autooxidation. However, Criegee successfully isolated hydroperoxide for the first time and also proposed and developed the mechanism of ozonolysis and OsO4 reagent of 1,2-dihydroxylation for alkenes. Then, hydroperoxide was employed in industrial synthesis of phenol and propylene oxide, the so called cumene and oxirane methods respectively. In the chemical laboratory, carbonic peracid is frequently used for the epoxiation of alkenes and Bayer-Villiger reaction of ketones. Instead of carbonic peracid, persulfate (caroate) with ketone resulted in the formation of dioxirane, which is a three membered cyclic peroxide. Singlet oxygen in dye-sensitized photooxygenation was verified as non-radical oxidation, which afforded hydroperoxide as well as four-membered cyclic peroxide via a concerted mecahnism. The four-membered peroxide called 1,2-dioxetanes produced light during decomposition, begging the chemistry of chemiluminescence. In biological systems, O2 serves a central role in aerobic respiration to make energy. Oxygen binding hemoprotein such as Hemoglobin, superoxo-Fe(Ⅲ) complex, transport bound oxygen to cells, which was chemically modeled by Collmann and others. In hem-containing monooxygenase, oxo O=Fe(V) complexes such as the P-450 enzyme catalyzes hydroxylation and epoxidation for the detoxification of metabolites. These were also chemically modeled by Groves and others. In synthetic organic chemistry, many oxo- and peroxometal O=M and O2M have been used in stoichiometric oxidation of alcohol to carbonyl compounds and alkene to epoxide and 1,2-diol. Finally, asymmetric epoxidation and dihydroxylation by Ti-tert-butyl hydroperoxide and OsO4 were achieved by Sharpless and coworkers. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 教育論文 | |||||
書誌情報 |
en : Science Journal of Kanagawa University 巻 31, p. 93-102, 発行日 2020-10-30 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1880-0483 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12068302 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
その他の言語のタイトル | ||||||
その他のタイトル | Organometallic Chemistry Based on Reaction Types and Anecdote of Discoveries (7) | |||||
出版者 | ||||||
出版者 | 神奈川大学総合理学研究所 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | Departmental Bulletin Paper |