{"_buckets": {"deposit": "ec855b97-7aae-476d-a8d8-1e2eda32e95d"}, "_deposit": {"created_by": 10, "id": "12531", "owners": [10], "pid": {"revision_id": 0, "type": "depid", "value": "12531"}, "status": "published"}, "_oai": {"id": "oai:kanagawa-u.repo.nii.ac.jp:00012531", "sets": ["1219"]}, "author_link": [], "item_3_alternative_title_20": {"attribute_name": "その他の言語のタイトル", "attribute_value_mlt": [{"subitem_alternative_title": "Geometrical Isomer of Open-Dawson Polyoxometalate"}]}, "item_3_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-06-30", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "50", "bibliographicPageStart": "47", "bibliographicVolumeNumber": "29", "bibliographic_titles": [{"bibliographic_title": "Science Journal of Kanagawa University", "bibliographic_titleLang": "en"}]}]}, "item_3_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "By the reaction of β-Keggin-type polyoxometalate (POM), [A-β-SiW9O34]10- with Fe3+ at pH 3, the β, β-isomer of open-Dawson POM containing the tetra-iron(III) cluster [{Fe4(OH2) (OH)5}(β, β-Si2W18O66)]9- (β, β-Fe4-open) was successfully synthesized as potassium salt and the molecular structure was determined. It was unequivocally characterized by complete elemental analysis, thermogravimetric and differential thermal analysis (TG/DTA), FTIR and UV-vis absorption spectroscopy, cyclic voltammetry, and X-ray crystallography. X-ray crystallography revealed that the {Fe4(H2O)(OH)5}7+ cluster ion was embedded in the open pocket moiety of the β, β-type open-Dawson POM [β, β-Si2W18O66]16- formed by the fusion of two tri-lacunary β -Keggin POMs, [A-β-SiW9O34]10-, via two W-O-W bonds. The β, β-open-Dawson POM corresponds to an opened structure of the usual γ-Dawson POM. β, β-Fe4-open is the first example of the geometrical isomer of the previously reported α, α-open-Dawson POM containing the tetra-iron(III) cluster [{Fe4(OH)6}(α, α-Si2W18O66)]10- (α, α-Fe4-open).", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_3_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "原著", "subitem_description_language": "ja", "subitem_description_type": "Other"}, {"subitem_description": "2017年度神奈川大学総合理学研究所共同研究助成論文", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_3_publisher_33": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "神奈川大学総合理学研究所", "subitem_publisher_language": "ja"}, {"subitem_publisher": "Research Institute for Integrated Science, Kanagawa University", "subitem_publisher_language": "en"}]}, "item_3_source_id_10": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA12068302", "subitem_source_identifier_type": "NCID"}]}, "item_3_source_id_8": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1880-0483", "subitem_source_identifier_type": "PISSN"}]}, "item_3_version_type_16": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "野宮, 健司", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "井上, 雄介", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "三原, 航平", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "宮前, 枝里子", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "新井, 裕喜", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "力石, 紀子", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "松永, 諭", "creatorNameLang": "ja"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-05-30"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "08 Open-Dawson 型ポリオキソメタレートの構造異性体.pdf", "filesize": [{"value": "1.8 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1800000.0, "url": {"label": "08 Open-Dawson 型ポリオキソメタレートの構造異性体", "url": "https://kanagawa-u.repo.nii.ac.jp/record/12531/files/08 Open-Dawson 型ポリオキソメタレートの構造異性体.pdf"}, "version_id": "f2969b0e-76f3-42d6-92fd-ceef1736a31d"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "polyoxometalate", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "open-Dawson structure", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "iron", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "geometrical isomer", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Open-Dawson型ポリオキソメタレートの構造異性体", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Open-Dawson型ポリオキソメタレートの構造異性体", "subitem_title_language": "ja"}, {"subitem_title": "Geometrical Isomer of Open-Dawson Polyoxometalate", "subitem_title_language": "en"}]}, "item_type_id": "3", "owner": "10", "path": ["1219"], "permalink_uri": "http://hdl.handle.net/10487/00015638", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2019-06-07"}, "publish_date": "2019-06-07", "publish_status": "0", "recid": "12531", "relation": {}, "relation_version_is_last": true, "title": ["Open-Dawson型ポリオキソメタレートの構造異性体"], "weko_shared_id": -1}
Open-Dawson型ポリオキソメタレートの構造異性体
http://hdl.handle.net/10487/00015638
http://hdl.handle.net/10487/00015638