Stereoselectivities in Catalytic Hydrogenation of Several Branched-Chain 6-Deoxyhex-5-enopyranosides. A Synthesis of Branched-Chain Methyl 6-Deoxy-β-L-hexopyranoside
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Hydrogenation of several 2-C, 3-C, and 4-C-methyl-branched 6-deoxyhex-5-enopyranosides in the presence of palladium–carbon in ethanol showed stereoselective formation of the corresponding 6-deoxy-β-L-hexopyranosides.